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Cold fluid is more viscous and can create what some people call "thermal shock" against warm tissue

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In intact HepG2 cells, the pan-flavoenzyme inhibitor, DPI, prevented the NFT-stimulated increase in glutathione levels, indicating the involvement of one or more of these enzymes in NFT-dependent activation of Nrf2 (Fig

J Neurophysiol 132(1):277

But as you have seen, this itself can be problematic considering just how many of these are asymptomatic not the source of the shoulder pain